WebJul 8, 2024 · When hypervalent iodine(iii) oxidants such as [bis(tert-butylcarbonyloxy)iodo]benzene, (diacetoxyiodo)benzene and [bis(trifluoroacetoxy)iodo]benzene were tested, the DMC yields were 52.8, 50.7 and ... WebApplication: Bis (tert-butylcarbonyloxy)iodobenzene is a hypervalent iodine reagent CAS Number: 57357-20-7 Molecular Weight: 406.26 Molecular Formula: C 16 H 23 IO 4 For Research Use Only. Not …
Pd(II)-Catalyzed Aminoacetoxylation of Alkenes Via Tether Formation
WebA lower reactivity was observed when PIDA was replaced with 2 equiv of bis(tert-butylcarbonyloxy)iodobenzene, affording the corresponding pivalate compound 2v in 38% yield as a single diastereoisomer. 23 A good conversion was achieved with PhI(mcpba) 2 providing 2w in 55% isolated yield and 4.5:1 dr. WebMay 5, 2024 · In contrast to that, Li et al. were able to conduct a para -selective fluorination of anilides using bis ( tert -butylcarbonyloxy)-iodobenzene (PhI (OPiv) 2) in combination with HF-pyridine as fluoride … brewhouse pa
Para‐Fluorination of Anilides Using Electrochemically …
Webbis(tert-butylcarbonyloxy)iodobenzene with tetrabutylammo- nium bromide or TEMPO triggers aminobromination or aminooxyamination reactions, respectively. Control experiments showed that the three reactions proceed through distinct mechanisms: the first process is ionic while the other two follow a radical manifold. WebMay 11, 2024 · When the reaction is performed in the presence of hypervalent iodine reagents such as PIFA ([bis(trifluoroacetoxy)iodo]benzene), PhI(NPhth) 2 and PIDP (bis(tert-butylcarbonyloxy)iodobenzene) much better yields were obtained (Table 1, entries 2–4), with PhI(OAc) 2 proving to be the best (Table 1, entry 5). WebBis(tert-butylcarbonyloxy)iodobenzene C16H23IO4 CID 11846058 - structure, chemical names, physical and chemical properties, classification, patents, literature, … brewhouse pismo beach